Semi F21-95 is the Standard for the classification of microelectronic clean environments according to their airborne molecular contaminant levels. The Standard is applicable in the specification of semiconductor clean environments which includes process tool environments as well as contamination control and measurement equipment. The Standard specifies four categories of material contaminants, being Acids, Bases, Condensables and Dopants. A description of the four main material contaminant categories is provided in the table below.
 

Category Description
Acids A corrosive material whose chemical reaction characteristics is that of an electron acceptor.
Bases A corrosive material whose chemical reaction characteristic is that of an electron donor
Condensables                                                     A substance (other than water) typically having a boiling point above room temperature at atmospheric pressure, capable of condensation on a clean surface
Dopants A chemical element which modifies the electrical properties of a semiconductor material

Classification is according to the maximum allowable total gas phase concentration of each category of material contaminant. The combination of a quantitative class for each of the four categories of contaminant results in a classification that describes the AMC level of that environment. The maximum cumulative gas phase concentration of the four categories may be different.

The classification system can be best explained as follows: Each contaminant category is designated by the letter ‘M’ followed by the letter A, B, C, or D which signifies the material as follows: A = Acids, B = Bases, C= Condensables, D= Dopants. The integer following the material category classification indicates the maximum total gas phase concentration in parts per trillion (ppt). For example, a category MB-10 has a maximum allowable total concentration of 10 parts per trillion for the category Bases.
 

Material
Category
Classification
1 (ppt)
Classification
10 (ppt)
Classification
100 (ppt)
Classification
1,000 (ppt)
Classification
10,000 (ppt)
Acids MA-1 MA-10 MA-100 MA-1,000 MA-10,000
Bases MB-1 MB-10 MB-100 MB-1,000 MB-10,000
Condensables MC-1 MC-10 MC-100 MC-1,000 MC-10,000
Dopants MD-1 MD-10 MD-100 MD-1,000 MD-10,000